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Online ISSN: 1099-0488    Print ISSN: 0887-6266
Journal of Polymer Science Part B: Polymer Physics
Volume 37, Issue 13, 1999. Pages: 1351-1356

Published Online: 25 May 1999

Copyright © 1999 John Wiley & Sons, Inc.

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Properties of polyvinylchloride in solution: an hydrodynamic and vibrational spectroscopy study
Vassiliki-Alexandra Glezakou 1, Maria Soutzidou 1, Christos Loukoutos 1, Ioannis Xexakis 1, Kyriakos G. Viras 1 2 *
1 National and Kapodistrian University of Athens, Chemistry Department, Physical Chemistry Laboratory, Panepistimiopolis, Athens 157 71 Greece
2Visiting Fellow, Department of Chemistry, University of Manchester, Manchester M13 9PL, United Kingdom
email: Kyriakos G. Viras (kvyr@arnold.phchem.uoa.gr)

* Correspondence to Kyriakos G. Viras, Visiting Fellow, Department of Chemistry, University of Manchester, Manchester M13 9PL, United Kingdom

Funded by:
 General Secretariat of Research and Technology of Greece; Grant Number: 93E 191

PVC; intrinsic viscosity; conformation; IR; Raman

The polymer polyvinylchloride has been studied in binary solvent mixtures and as a function of temperature in solution. A discontinuity of the polymer chain dimensions has been observed, as measured by hydrodynamic methods. This phenomenon is further examined by infrared and Raman spectroscopy. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 37: 1351-1356, 1999

Received: 26 April 1994; Revised: 11 January 1999; Accepted: 19 January 1999

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