Far-infrared interaction-induced absorption spectra of CS2---C6H6 liquid mixtures
Evangelos Zoidisa, Jannis Samiosb and Thomas Dorfmüllera,
a Fakultät für Chemie, Physikalische Chemie I, Universität Bielefeld, Postfach 100131, W-4800 Bielefeld, Germany
b Department of Chemistry, Physical and Theoretical Chemistry, University of Athens, Athens, Greece
Received 11 July 1991; revised 8 September 1992. Available online 21 January 2002.
Far-infrared absorption spectra of liquid mixtures CS2---C6H6 at three concentrations display excess values of the absorption and the effective dipole moment with respect to both components. These spectral features are interpreted in terms of the dynamics of the local environmental fluctuation. We believe that these interaction-induced spectra reflect the formation and the decay of transient clusters rather than binary complexes.
Correspondence to: T. Dorfmüller, Fakultät für Chemie, Physikalische Chemie I, Universität Bielefeld, Postfach 100131, W-4800 Bielefeld, Germany.